RuCl3-Catalyzed Oxidation of Iodoarenes with Peracetic Acid: New Facile Preparation of Iodylarenes.
โ Scribed by Alexey Y. Koposov; Rashad R. Karimov; Andrey A. Pronin; Tatyana Skrupskaya; Mekhman S. Yusubov; Viktor V. Zhdankin
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 20 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Pteroylglutamic acid was labeled with deuterium by trifluoroacetic acid-catalyzed exchange with deuterium oxide. The product, pteroylglutamic acid-3',5'-H2, was selectively labeled with deuterium in the 4-aminobenzoyl portion of the molecule; there was no evidence for isotope incorporation at C or
A one pot oxidation of cyclic unsaturated carbonyl and carboxylic compounds with ruthenium (III)-chloride and peracetic acid to the corresponding ยขx-oxo-ene-diols (aci-reductones) has been developed.