RuCl3 catalyses aldol condensations of aldehydes and ketones
β Scribed by Nasser Iranpoor; Foad Kazemi
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 288 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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β¦ Synopsis
Anhydrous RuC13 catalyses the efficient cross aldol condensations of different ketones with various aromatic aldehydes in sealed tube under solvent free conditions without the occurrence of any self condensations.
Regioselective self condensation reaction of some ketones and aldehydes are also described. The catalytic effect of Ru(III) is shown by performing similar reactions under thermal conditions without catalyst.
π SIMILAR VOLUMES
The reaction of tin enolates of cyclohexanone or propiophenone with benzaldehyde at -78'C gives predominately the threo aldol diastereomer.
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