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RuCl3 catalyses aldol condensations of aldehydes and ketones

✍ Scribed by Nasser Iranpoor; Foad Kazemi


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
288 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis


Anhydrous RuC13 catalyses the efficient cross aldol condensations of different ketones with various aromatic aldehydes in sealed tube under solvent free conditions without the occurrence of any self condensations.

Regioselective self condensation reaction of some ketones and aldehydes are also described. The catalytic effect of Ru(III) is shown by performing similar reactions under thermal conditions without catalyst.


πŸ“œ SIMILAR VOLUMES


Diastereoselective aldol condensations o
✍ Sharada Shenvi; J.K. Stille πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 218 KB

The reaction of tin enolates of cyclohexanone or propiophenone with benzaldehyde at -78'C gives predominately the threo aldol diastereomer.