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[RuCl 2 (PPh 3 )(PNN‘)] Complexes as Efficient Catalysts in Transfer Hydrogenation of Ketones

✍ Scribed by Del Zotto, Alessandro; Baratta, Walter; Ballico, Maurizio; Herdtweck, Eberhardt; Rigo, Pierluigi


Book ID
120359635
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
147 KB
Volume
26
Category
Article
ISSN
0276-7333

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Chiral N,N%-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.