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Ru(CH3CN)3Cl3, preparation and use as a mediator for the electrooxidation of hydrocarbons

✍ Scribed by L Appelbaum; C Heinrichs; J Demtschuk; M Michman; M Oron; H.J Schäfer; H Schumann


Book ID
108356248
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
318 KB
Volume
592
Category
Article
ISSN
0022-328X

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The Structure of fac-Ce(OAsPh3)3Cl3·CH3C
✍ R.R. Ryan; E.M. Larson; G.F. Payne; J.R. Peterson 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 532 KB

Ce(OAsPhs)sCls.CHsCN, Pi, with cell parameters a = 11.614(l), b = 12.009(2) and c = 20.991(3) A, 01= 89.08(l), /3 = 88.50(l), 7 = 64.40'(2), and Z = 2. Refinement of 320 parameters for 4710 reflections converged to R = 0.052 and R, = 0.067. This is the first example of a Ln(ll1) chloride complex wit