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Ru–BINAP-catalyzed asymmetric hydrogenation of keto esters in high pressure carbon dioxide

✍ Scribed by Turova, Olga V.; Kuchurov, Ilya V.; Starodubtseva, Eugenia V.; Ferapontov, Vladimir A.; Ikonnikov, Nikolai S.; Zlotin, Sergei G.; Vinogradov, Maxim G.

Book ID
119325077
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
266 KB
Volume
22
Category
Article
ISSN
0959-9436

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The role of the solvent in the asymmetri
The role of the solvent in the asymmetric hydrogenation of β-keto esters with Ru-BINAP
✍ Adi Wolfson; Ivo F.J. Vankelecom; Shimona Geresh; Pierre A. Jacobs 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 103 KB

The influence of the solvent on the asymmetric hydrogenation of methyl acetoacetate, as a representative ␤-keto esters, with Ru-BINAP was studied. The highest activities were measured when the reaction proceeded in methanol, ethanol or isopropanol. These solvents, which also act as proton donors, ac