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ChemInform Abstract: Ru-Catalyzed Asymmetric Hydrogenation of γ-Heteroatom Substituted β-Keto Esters.

✍ Scribed by Weizheng Fan; Wanfang Li; Xin Ma; Xiaoming Tao; Xiaoming Li; Ying Yao; Xiaomin Xie; Zhaoguo Zhang


Publisher
John Wiley and Sons
Year
2012
Weight
35 KB
Volume
43
Category
Article
ISSN
0931-7597

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Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II). -The asymmetric hydrogenation of β-keto esters or related compounds to the corresponding secondary alcohols is readily achieved with a homogeneous Ru-catalyst based on a P-chiral bis(dialkylph