Rubidium uranyl phosphates and arsenates with polymeric tetrahedral anions: Syntheses and structures of Rb4[(UO2)6(P2O7)4(H2O)], Rb2[(UO2)3(P2O7)(P4O12)] and Rb[(UO2)2(As3O10)]
β Scribed by Evgeny V. Alekseev; Sergey V. Krivovichev; Wulf Depmeier
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 484 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0022-4596
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Two new, noncentrosymmetric, rubidium titanium phosphate phases have been synthesized by hydrothermal and flux methods and structurally characterized by single crystal X-ray diffraction methods. \(\mathrm{Rb}_{2} \mathrm{Ti}_{3} \mathrm{O}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{HPO}_{4}\ri
Three new uranyl tungstates, A 8 [(UO 2 ) 4 (WO 4 ) 4 (WO 5 ) 2 ] (A ΒΌ Rb (1), Cs (2)), and Rb 6 [(UO 2 ) 2 O(WO 4 ) 4 ] (3), were prepared by hightemperature solid-state reactions and their structures were solved by direct methods on twinned crystals, refined to R 1