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Rubidium uranyl phosphates and arsenates with polymeric tetrahedral anions: Syntheses and structures of Rb4[(UO2)6(P2O7)4(H2O)], Rb2[(UO2)3(P2O7)(P4O12)] and Rb[(UO2)2(As3O10)]

✍ Scribed by Evgeny V. Alekseev; Sergey V. Krivovichev; Wulf Depmeier


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
484 KB
Volume
182
Category
Article
ISSN
0022-4596

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Three new uranyl tungstates, A 8 [(UO 2 ) 4 (WO 4 ) 4 (WO 5 ) 2 ] (A ΒΌ Rb (1), Cs (2)), and Rb 6 [(UO 2 ) 2 O(WO 4 ) 4 ] (3), were prepared by hightemperature solid-state reactions and their structures were solved by direct methods on twinned crystals, refined to R 1