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One-dimensional chains in uranyl tungstates: Syntheses and structures of A8[(UO2)4(WO4)4(WO5)2] (A=Rb, Cs) and Rb6[(UO2)2O(WO4)4]

✍ Scribed by Evgeny V. Alekseev; Sergey V. Krivovichev; W. Depmeier; T. Armbruster; H. Katzke; Evgeny V. Suleimanov; Evgeny V. Chuprunov

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 670 KB
Volume: 179
Category: Article
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2006.05.015

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✦ Synopsis

Three new uranyl tungstates, A 8 [(UO 2 ) 4 (WO 4 ) 4 (WO 5 ) 2 ] (A ¼ Rb (1), Cs (2)), and Rb 6 [(UO 2 ) 2 O(WO 4 ) 4 ] (3), were prepared by hightemperature solid-state reactions and their structures were solved by direct methods on twinned crystals, refined to R 1

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