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Ru II -SDP-Complex-Catalyzed Asymmetric Hydrogenation of Ketones. Effect of the Alkali Metal Cation in the Reaction

✍ Scribed by Xie, Jian-Hua; Liu, Sheng; Huo, Xiang-Hong; Cheng, Xu; Duan, Hai-Feng; Fan, Bao-Ming; Wang, Li-Xin; Zhou, Qi-Lin


Book ID
120998172
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
216 KB
Volume
70
Category
Article
ISSN
0022-3263

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Chiral amino amides for the ruthenium(II
✍ Jincheng Mao; Jun Guo πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 119 KB πŸ‘ 2 views

## Abstract The chiral amino amide **3** was derived from L‐proline and used for the [RuCl~2~(__p__‐cymene)]~2~‐catalyzed asymmetric transfer hydrogenation of prochiral ketones performed in water. Moderate to good chemical selectivities (up to 95% yield) and enantioselectivities (up to 90% ee) were