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(RS,RS)-5-[Hydroxy(4-methylphenyl)methyl]furan-2(5H)-one

✍ Scribed by Ollevier, Thierry ;Bouchard, Jean-Emmanuel ;Desyroy, Valerie ;Tessier, Christian

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
349 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of the racemic title compound, C~12~H~12~O~3~, allowed the determination of the relative configuration at the two stereogenic centers. For the R,R isomer, the O—C—C—O and C—C—C—C torsion angles around the bond between the two methine C atoms are 62.38 (15) and −175.49 (13)°, respectively. The furan and tolyl groups are almost perpendicular, with a dihedral angle of 79.39 (5)°. Strong and linear intermolecular O—H...O hydrogen bonding (H...O = 2.04 Å and O—H...O = 177°) is observed between the hydroxyl group and the C=O oxygen.

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