(4RS,5RS)-4-Benzyl-5-(4-tolylthiocarbonyl)oxazolidin-2-one
✍ Scribed by Clegg, William ;Elsegood, Mark R. J.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 178 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The crystal structure of the racemic title compound, C~12~H~12~O~3~, allowed the determination of the relative configuration at the two stereogenic centers. For the __R,R__ isomer, the O—C—C—O and C—C—C—C torsion angles around the bond between the two methine C atoms are 62.38 (15) and −175.49 (13)°
The polysubstituted piperidine enol ring in the title compound, C~29~H~31~NO~3~S, adopts a twisted half-chair conformation. The crystal structure is stabilized by van der Waals and weak C—H...π interactions. An intramolecular O—H...O interaction generates an __S__(6) graph-set motif.