Rovibrational energy and spectroscopic constant calculations of CH4 ⋯ CH4, CH4 ⋯ H2O, CH4 ⋯ CHF3, and H2O ⋯ CHF3dimers
✍ Scribed by Cunha, Wiliam F.; Gargano, Ricardo; Garcia, Edgardo; Politi, José R. S.; Albernaz, Alessandra F.; Martins, João B. L.
- Book ID
- 125351026
- Publisher
- Springer-Verlag
- Year
- 2014
- Tongue
- English
- Weight
- 613 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1610-2940
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## Abstract The Laser Photolysis‐Shock Tube technique coupled with H‐atom atomic resonance absorption spectrometry has been used to study the reaction, H + CH~4~ → CH~3~ + H~2~, over the temperature range, 928–1697 K. Shock‐tube studies on the reverse of this reaction, CH~3~ + H~2~ → H + CH~4~, usi
The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms