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Routes of catalytic hydrogen addition to α, β-unsaturated ketones

✍ Scribed by L. Kh. Freidlin; L. I. Gvinter; V. A. Zamureenko; L. N. Suvorova


Book ID
112437874
Publisher
Springer
Year
1976
Tongue
English
Weight
235 KB
Volume
25
Category
Article
ISSN
1573-9171

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Catalytic enantioselective conjugate add
✍ Marco Bandini; Matteo Fagioli; Paolo Melchiorre; Alfonso Melloni; Achille Umani- 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 174 KB

Chiral [Al(salen) Cl] complex (10 mol%) in the presence of 2,6-lutidine (10 mol%) was found to be effective in catalysing the enantioselective Friedel-Crafts-type conjugate addition of indoles (3) to (E)-arylcrotyl ketones (2), furnishing the corresponding b-indolyl ketones in excellent yield and h