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Routes for the formation of 1,2-oxaphospholene derivatives by the reaction ofβ-keto alcohols with the acid chlorides of trivalent phosphorus acids

✍ Scribed by B. A. Arbuzov; N. I. Rizpolozhenskii; A. O. Vizel'; K. M. Ivanovskaya; F. S. Mukhametov; É. I. Gol'dfarb


Book ID
112420983
Publisher
Springer
Year
1971
Tongue
English
Weight
633 KB
Volume
20
Category
Article
ISSN
1573-9171

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The reaction of lithium ester enolates w
✍ Michael W. Rathke; Jeffrey Deitch 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 158 KB

Lithium ester enolates, prepared by the reaction of lithium N-isopropylcyclohexylamide (LIICA) with esters at -78' (eq. 1); react with acid chlorides at this same low temperature to provide satisfactory yields of the corresponding S-keto esters (eq. II). This procedure represents an exceedingly vers