Vibrational overtone transitions of OCS in the near infrared, 10 000-14 000 cm 01 , are observed for the first time by means of the photoacoustic technique. The spectra are analyzed using molecular parameters and Hamiltonions derived for energy levels below 5000 cm 01 . It is demonstrated that the m
Rotationally resolved overtone transitions of 70GeH4 in the visible and near-infrared
✍ Scribed by A. Campargue; J. Vetterhöffer; M. Chenevier
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 336 KB
- Volume
- 192
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The Au ocH = 6,7 and 8 overtone transitions of natural germane and of mono isotopic germane "'GeH., have been measured with rotational resolution by intracavity laser absorption spectroscopy. The AvocH= 6 and 7 rotational structure is found to be that of a pseudo-symmetric top as expected for this molecule close to the local mode limit. On the other hand the Au,,,= 8 shows a more complicated structure which has not yet been analyzed.
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