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Rotationally resolved high (n > 100) Rydberg states of benzene

✍ Scribed by R. Neuhauser; H.J. Neusser

Book ID
103034874
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
509 KB
Volume
253
Category
Article
ISSN
0009-2614

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✦ Synopsis

Using sub-Doppler double resonance excitation individual high-n Rydberg states were excited in a polyatomic molecule. Even for a selected JK intermediate rovibrational state in benzene, C6D6, several Rydberg series are observed converging to different limits. The pulsed field ionization signal has a decay time that is longer than expected from measured lifetimes of low Rydberg states of benzene and ascribed to/-mixing in the residual electric stray field.

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