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Rotational l-type doubling in the kl = +1 levels of the ν4 state of PH3

✍ Scribed by S.P. Belov; A.F. Krupnov; D. Papoušek; Š. Urban; G. Cazzoli

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
266 KB
Volume
98
Category
Article
ISSN
0022-2852

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Direct I-type doubling transitions in th
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The first three direct Z-type doubling transitions in the "4 = 1 state of PH3 have been measured. The Z-type doubling constant q4 has been evaluated to be 5267.10(60) MHz.

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A representation of the effective rotational Hamiltonian in the form of optimum versions of a rational series of the perturbation theory is suggested for nonisolated molecular states. This representation is used to analyze the most complete set of precise transition frequencies in the rotational spe

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Direct /-type doubling transitions in the 06 = 1 state of CF379Br, CF3SIBr and CF3I have been observed using the technique of Fourier transform microwave spectroscopy in the range 4.5-8 GHz. The transitions covered a range of J values from 38-47 for both isotopomers of CF3Br and from 40-51 for CFaI.