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Rotational isomerism in 2-chloro-4-methylpentane and 3-chloro-2-methylpentane

โœ Scribed by G.A. Crowder


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
157 KB
Volume
53
Category
Article
ISSN
0022-2860

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๐Ÿ“œ SIMILAR VOLUMES


Kinetic and thermodynamic study of 2-bro
โœ Lรญdia C. Albuquerque; Luisa C. Moita; Ana N. Simรตes; Raquel C. Gonรงalves; Eugรฉni ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 91 KB ๐Ÿ‘ 1 views

Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info

Rotational isomerismโ€”XII Rotamer energie
โœ R. J. Abraham; W. L. Oliver Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 413 KB

The complete analysis of the NMR spectrum of CH,CI.CFBr.CH, in CCI, and acetone is given. The long range 'JHH couplings in this molecule differ considerably and surprisingly are both positive. An analysis of the solvent dependence of the couplings enables the rotamer couplings and energies to be obt