Rotational isomerism in 2-chloro-4-methylpentane and 3-chloro-2-methylpentane
โ Scribed by G.A. Crowder
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 157 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-2860
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๐ SIMILAR VOLUMES
Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info
The complete analysis of the NMR spectrum of CH,CI.CFBr.CH, in CCI, and acetone is given. The long range 'JHH couplings in this molecule differ considerably and surprisingly are both positive. An analysis of the solvent dependence of the couplings enables the rotamer couplings and energies to be obt