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Conformational analysis of 2-chloro-4-methylpentane and 2-bromo-4-methylpentane

✍ Scribed by G.A. Crowder; R.M.P. Jaiswal


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
495 KB
Volume
99
Category
Article
ISSN
0022-2860

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Kinetic and thermodynamic study of 2-bro
✍ LΓ­dia C. Albuquerque; Luisa C. Moita; Ana N. SimΓ΅es; Raquel C. GonΓ§alves; EugΓ©ni πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 91 KB πŸ‘ 1 views

Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info