Rotational intensities of a magnetic rotation spectrum for a diatomic molecule
✍ Scribed by D.A. Hutchinson; H.F. Hameka
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- English
- Weight
- 643 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
The potential model of G. Thompson et al. [J. Mol. Spectrosc. 124, 130-138 (1987)] for an analysis of the vibrational-rotational and the rotational spectra of diatomic molecules is modified by an algebraic WKB treatment of the Schro ¨dinger equation given by Watson's effective Hamiltonian. A compact
Differences between vibrational and rotational rehsation patterns disappex and similarities are reveaIed by\_trxtsforming from stite to er.ergy distributions\_ This IblIows from the constant state density of both osciilators and rotors and the exponential gap 1zw governing their relaxation A simple.
The problem of the determination of the vibration-rotation eigenvalue in diatomic molecules is considered. An eigenvalue equation totally independent from the eigenfunction is written for any potential, analytical or numerical. This equation uses uniquely the vibration-rotation canonical functions;