This paper concerns rotational energy levels and line intensities for electronic, vibrational, and microwave transitions in an open-shell complex consisting of an open-shell diatomic molecule and a closed-shell partner. The electronic state of the open-shell diatomic fragment is a 2Sϩ1 ⌺ state, wher
Rotational intensity factors for 2Σ−4Σ transitions in diatomic molecules
✍ Scribed by V.P. Bellary; T.K. Balasubramanian
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 162 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-4073
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A Dunham treatment of an effective Hamiltonian for diatomic molecules in 2 ⌺ states that includes contributions of the Born-Oppenheimer breakdown has yielded an expression for vibrational-rotational energy by an expansion in powers of (v ϩ state and k ϭ 0, 1, . . . , j. Analytic expressions for the
Linestrengths have been measured for 12 bands of \(\mathrm{N}_{2} \mathrm{O}\) using a Fourier transform spectrometer, with an effective response function width of about \(5 \times 10^{-3} \mathrm{~cm}^{-1}\). The observed bands for \({ }^{14} \mathrm{~N}_{2}{ }^{16} \mathrm{O}\) are the cold bands
Linestrengths have been measured for five bands of \({ }^{14} \mathrm{~N}_{2}{ }^{16} \mathrm{O}\) using a Fourier transform spectrometer, with an effective response function width of about \(5 \times 10^{-3} \mathrm{~cm}^{-1}\). The observed bands are the cold band \(\nu_{2}+\nu_{3}\) and the hot b