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Rotational dynamics of methyl groups in m-xylene

✍ Scribed by Kirstein, O.; Prager, M.; Dimeo, R. M.; Desmedt, A.

Book ID
127327933
Publisher
American Institute of Physics
Year
2005
Tongue
English
Weight
429 KB
Volume
122
Category
Article
ISSN
0021-9606

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Rotational dynamics of the methyl group
Rotational dynamics of the methyl group in the 4-methyl pyridine crystal
✍ L. Soulard; F. Fillaux; G. Braathen; N. Le CalvΓ©; B. Pasquier πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 528 KB

Raman spectra below 150 cm-' of the 4-methyl pyridine crystal, and its deuterated derivative (d,), at various temperatures from 276.8 K (melting point) to 5 K are presented and vibrational assignments proposed. Three crystal phases are observed between 5-100 K (III), loo-254 K (II) and 254-276.8 K (