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Methyl group rotation and whole molecule dynamics in methyl bromide hydrate‡‡

✍ Scribed by Prager, M.; Desmedt, A.; Allgaier, J.; Russina, M.; Jansen, E.; Natkaniec, I.; Pawlukojc, A.; Press, W.

Book ID
126659657
Publisher
Taylor and Francis Group
Year
2007
Tongue
English
Weight
325 KB
Volume
80
Category
Article
ISSN
0141-1594

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✍ L. Soulard; F. Fillaux; G. Braathen; N. Le Calvé; B. Pasquier 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 528 KB

Raman spectra below 150 cm-' of the 4-methyl pyridine crystal, and its deuterated derivative (d,), at various temperatures from 276.8 K (melting point) to 5 K are presented and vibrational assignments proposed. Three crystal phases are observed between 5-100 K (III), loo-254 K (II) and 254-276.8 K (