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Rotational distributions in photodissociation: application to ICN

✍ Scribed by Michael D. Morse; Karl F.Freed; Yehuda B. Band

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
588 KB
Volume
44
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES

ICN photodissociation at 193 nm; CN(B2Ξ£)
ICN photodissociation at 193 nm; CN(B2Ξ£) rotational distributions and fluorescence polarization
✍ Mark Lambert; Brian Callen; H. Dugan; S.V. Filseth; F.J. Morgan; C.M. Sadowski πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 413 KB

The rotational distribution of CN( B "C, v=O) dissociated from ICN at I93 nm is well represented by a thermal rotational distribution for T= 250 K, giving an average energy of I75 cm-'. The energy of the highest rotational state detected (N= 28) suggests that some or all of the molecules dissociated

Ab initio potential energy surfaces for
Ab initio potential energy surfaces for rotational excitation of CN product in the A-band photodissociation of ICN
✍ Satoshi Yabushita; Keiji Morokuma πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 626 KB

Potential energy surfaces of low-lying excited states of ICN have been calculated for linear and bent dissociation using the ab initio spin-orbit CI method with the effective spin-orbit Hamiltoman. Contrary to popular belief, all the relevant excited surfaces are bent in the Franck-Condon region and