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Rotational diffusion in liquid CCl3F

✍ Scribed by R.E.D. McClung

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
447 KB
Volume
19
Category
Article
ISSN
0009-2614

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✦ Synopsis

The 35C1 and "F nuclear relaxation data for liquid CC&F are ar&zed in terms of the extended rotational diffusion model for symmetric top molecules. The/-diffusion limit is shown to be in accordance with the relaxation data, but the W-diffusion limit is incompatible with the data. The "1: spin-rotation coupling constants obtained from the analysis are consistent with predictions based on chemical shift.

In the first paragraph of section 4, .?he values of I', Y and Z should be changed to read 1 Xl = 0.10127, I Yl = 0.02153, and IZ[ = 0.0'7974 cm-1 [ 11. The values of D and E given in the same section are correct.

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