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Extended rotational diffusion and dielectric relaxation in liquid solutions

✍ Scribed by Yuri P. Kalmykov; James McConnell

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
904 KB
Volume
193
Category
Article
ISSN
0378-4371

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✦ Synopsis

The complex dielectric permittivity for a dilute solution of polar molecules dissolved in a nonpolar solvent is calculated in the context of a generalized J-diffusion model. This model takes into account both inertial effects and finite duration of collisions. The theory is compared with experimental far-infrared absorption spectra of HCl and DC1 in nonpolar solvents.

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