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Rotational barriers and conjugation in polyphenylene oligomers

โœ Scribed by S.T. Pasco; G.L. Baker


Book ID
117541348
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
204 KB
Volume
84
Category
Article
ISSN
0379-6779

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Conformational populations and rotationa
โœ T.Bruce Grindley ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

The trans conformations of methyl, ethyl and isopropyl formate were shown to be present in equilibrium in a polar solvent with the cis conformations to significant (> 1% at 230K) but much lower extents than for t-butyl fox-mate; rotational barriers for the former compounds are greater. Extensive in