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Rotational barrier in an allyl radical

✍ Scribed by Sustmann, Reiner; Trill, Heinrich

Book ID
126878673
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
386 KB
Volume
96
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

The rotational barrier of the allyl anio
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Rotational Analysis of Ξ½13 of Allyl Radi
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Transient infrared laser spectroscopy near 3100 cm Οͺ1 has been used to observe the 13 band of the allyl radical. The rotational structure has been assigned and analyzed. Reliable assignments of both asymmetry components have been made for the subbands with K a Ο­ 0-5 and 7-10. Upper state rotational

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✍ Paul D. Sullivan; Joseph Y. Fong πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 216 KB

Molecular orbital theory shows that the conformation of, and barriers to rotation in, radical ions of biphenyl derivatives are greatly different from those of the neutral compounds. The results are consistent with the ESR results on the cation radicals of some substituted biphenyis.