✦ LIBER ✦

[1-2H]-Allyl radical: barrier to rotation and allyl delocalization energy

✍ Scribed by Korth, Hans-Gert; Trill, Heinrich; Sustmann, Reiner

Book ID: 126116497
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 849 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00405a032

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Ab initio calculations of the barriers t

Ab initio calculations of the barriers to rotation in 1,1-difluoroallyl radical and an analysis of the factors that govern rotational barriers in fluorinated allylic radicals

✍ Nicolaides, Athanassios; Borden, Weston Thatcher 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 629 KB

Theoretical analysis of the energy barri

Theoretical analysis of the energy barriers for the rotational isomerization of the allyl and the 1-cyano-, 1-hydroxy- and 1-cyano-1-hydroxyallyl radicals

✍ Daniel J. Pasto 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB 👁 2 views

An ab initio computational study was carried out on the ground-and transition-state structures for the rotational isomerization of the allyl and the 1-cyano, 1-hydroxy-and 1-cyano-1-hydroxyallyl radical systems in an attempt to gain an understanding of the factors affecting the relative energy barri

The energy barrier to combination of all

The energy barrier to combination of allylic radicals. Relative rates of rotation and ring closure of a rotameric pair of diradicals in the oxy-Cope rearrangement

✍ Berson, Jerome A.; Walsh, Edward J. 📂 Article 📅 1968 🏛 American Chemical Society 🌐 English ⚖ 277 KB

The dissociation of 3-chloro-1-butene an

The dissociation of 3-chloro-1-butene and the resonance energy of the chloro-allyl radical

✍ A. B. Trenwith 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 448 KB

Methane is a primary product of pyrolysis of 3-chloro-I-butene at temperatures in the range 776-835'K, and from its rate of formation values have been obtained for the limiting high-pressure rate constant of the reaction (1) CH$CHClCH=CHZ \* .CH3 + .CHCICH=CHZ These may be represented by the express

Kinetics of the I2-catalyzed isomerizati

Kinetics of the I2-catalyzed isomerization of allyl chloride to cis- and trans-1-chloro-1-propene. The stabilization energy of the chloroallyl radical

✍ Ze'ev B. Alfassi; David M. Golden; Sidney W. Benson 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 664 KB

## Abstract The I~2~‐catalyzed isomerization of allyl chloride to __cis__‐ and __trans__‐ l‐chloro‐l‐propene was measured in a static system in the temperature range 225–329°C. Propylene was found as a side product, mainly at the lower temperatures. The rate constant for an abstraction of a hydroge

Theoretical studies of radical recombina

Theoretical studies of radical recombination reactions. 4. An AM1/CI study of reactions of benzylic and allylic radicals. An intrinsic barrier to bond formation

✍ Huang, X. L.; Dannenberg, J. J. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 600 KB