Rotation-translation spectra of polar molecules in liquids
โ Scribed by S.G. Kroon; J. Van der Elsken
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 310 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Vibrational deactivation probabiljties are caiculated for N2. Olr C12, I2 in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy I+ leased. even for the heaviest diatomics.
Quantum close-coupling c3Icuhtions are presented which verify that the rotational polartriution observed in recent experiments on NO-Ag(I 11) scattering is due primarily to rzv conservation. However a dramatic dependena of rotational transitions on initial q in some surfwe collisions is also indicat
## Vlbrational-rotatlonal couphng, due to the fact that the center of interaction IS displaced from the center of mass in a heteronuclear diitomrc molecule, provides a mechanism for nonradiatwe vibrational relazxation of diitomic impurities in matrlces. A theoretical expresaon for the rate constan