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Rotation of methyl groups in hexamethylbenzene

✍ Scribed by Melissas, V.; Faegri, K.; Almloef, J.


Book ID
127363816
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
351 KB
Volume
107
Category
Article
ISSN
0002-7863

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On the gearing of methyl groups in hexam
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## Abstract Empirical force field calculations were performed on hexamethylbenzene to elucidate the internal motions of the methyl groups. When the benzene ring is constrained to be planar (as in solid‐phase studies), the methyl groups undergo a geared, disrotatory motion. When this constraint is r