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Infra-red evidence for internal rotation of CH3 groups in solid hexamethylbenzene

✍ Scribed by R.C. Leech; D.B. Powell; N. Sheppard

Publisher
Elsevier Science
Year
1966
Weight
258 KB
Volume
22
Category
Article
ISSN
0371-1951

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πŸ“œ SIMILAR VOLUMES

Internal Rotation of the Hydroxyl Group
Internal Rotation of the Hydroxyl Group in Isopropanol and the Chirality of the Gauche Form: Fourier Transform Microwave Spectroscopy of (CH3)2CHOD
✍ Eizi Hirota; Yoshiyuki Kawashima πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 272 KB

The rotational spectrum of the deuterated isopropanol (CH 3 ) 2 CHOD has been observed by Fourier transform microwave spectroscopy and analyzed to yield tunneling splitting of 4431.4613 (17) MHz, between the antisymmetric and the symmetric gauche forms, which is much larger than the 2400 MHz estimat