Perturbation of the internal vibrations of (CH3)2S and (CH3)2Se in matrix-isolated complexes with H2O and HCl: Indirect evidence for the trans lone pair effect in (CH3)2X molecules

Evidence for complex formation in the re

Evidence for complex formation in the reactions of CH+3 and CD+3 with CH3OH, CD3OD, and C2H5OH

✍ Richard D. Smith; Jean H. Futrell 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 447 KB

Product distributions for the reactions of CH$ and CDf with methanol, methanol-da, and ethanol studied in a tandemkm CpdOtrOTl resonance mass SpeCtrOmeter are reported. The major reaction pathways may 5c rationalized in terms of 3x1 intermediate species havving a pro&mated ether structure. The react