Room temperature synthesis and solid-state structure of Ni2P2O6·12H2O
✍ Scribed by J.M. Haag; G.C. LeBret; D.A. Cleary; B. Twamley
- Book ID
- 108195217
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 222 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0022-4596
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## Abstract Two 2D Anderson polyoxomolybdate‐based compounds, [{Ni(H~2~O)~4~}~2~{Ni(OH)~6~Mo~6~O~18~}]·4H~2~O (1) and [Ni(H~2~O)~6~][Ag~2~{Ni(OH)~6~Mo~6~O~18~}]·8H~2~O (2), were synthesized and characterized by elemental analysis, IR spectroscopy, SEM, and single‐crystal XRD. Their thermal behavior
A new compound containing polyoxovanadoborate anion was synthesized and characterized by single-crystal X-ray diffraction analysis. A water molecule at the center of the anion was precisely determined. The crystals of the new compound belong to the monoclinic system, space group P2 1 /n with a=1.350