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Room-Temperature Surface-Erosion Route to ZnO Nanorod Arrays and Urchin-like Assemblies

✍ Scribed by Zhengquan Li; Yue Ding; Yujie Xiong; Qing Yang; Yi Xie


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
271 KB
Volume
10
Category
Article
ISSN
0947-6539

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✦ Synopsis


Abstract

A solution surface‐erosion route was successfully employed to produce one‐dimensional (1D) ZnO nanostructures. ZnO nanorod arrays and three‐dimensional urchin‐like assemblies could be selectively obtained with different manipulations. In this process, zinc foil was introduced to an organic solution system and acted both as a reactant and substrate to support the 1D nanostructures obtained. This method, without any template, apparatus, surfactants, or additional heterogenous substrates, has greatly simplified the preparation of oriented 1D ZnO nanostructures. In particular, this simple route could be carried out at room temperature over a period as short as several minutes, thus it could be conveniently transferred to industrial applications. The possible formation mechanism, erosion process, and influence factors were also investigated.


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**A high‐quality ZnO nanorod array (NRA)** has been successfully grown on a Si wafer by a wet‐chemical process, where the Si wafer was dip‐coated with 4 nm sized ZnO nanoparticles as a buffer and seed layer prior to the crystal growth. It is found that the as‐prepared ZnO NRA has a threshold power d