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Room temperature polymerization of norbornene with a hydride-bridged dinuclear ruthenium complex system

✍ Scribed by Chen, Jinsen; Chen, Xun; Zhu, Congzhi; Zhu, Jin

Book ID
125821965
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
646 KB
Volume
394
Category
Article
ISSN
1381-1169

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## Abstract Reactions of the thiolate‐bridged diruthenium complex [Ru(py^bu^S~4~)]~2~ (1) {py^bu^S~4~^2−^ = 2,6‐bis[(3,5‐di‐__tert__‐butyl‐2‐sulfanylphenyl)thiomethyl]pyridine(2−)} with small‐molecule ligands L afforded the corresponding mononuclear complexes [Ru(L)(py^bu^S~4~)] [L = H^−^ (2); CH~3