Role of the trichlorosilyl radical and dichlorosilylene in gas-phase reactions of trichlorosilane
โ Scribed by Joachim Heinicke; Barbara Gehrhus
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 732 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0165-2370
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๐ SIMILAR VOLUMES
A rate constant for the epoxidation of acrolein by acetylperoxyl radicals has been determined to be k 4 ฯญ (1.3 ฯฎ 0.9) ฯซ 10 4 dm 3 mol ฯช1 s ฯช1 at 383 K, which is anomalously fast in comparison with the epoxidation of alkenes. Abstraction of the acyl hydrogen atom from acrolein by acetylperoxyl radica
The kinetics of chlorine atom abstraction from the chloromethanea (ClM), CCl,, CHCl,, CHZC12, and CH3Cl by radiolytically generated trichlorosilyl radicals was studied in the liquid phase by a competitive method. Arrhenius parameters of chlorine atom abstraction from chloroinethanes relative to that