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Electronic quenching and chemical reactions of SiH radicals in the gas phase

โœ Scribed by Masahiro Nemoto; Atsushi Suzuki; Hiroshi Nakamura; Kazuhiko Shibuya; Kinichi Obi


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
462 KB
Volume
162
Category
Article
ISSN
0009-2614

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Kinetics of some reactions of vinyl and
โœ Lajos Szirovicza ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 539 KB

Vinyl and isopropyl radicals were generated by the pyrolysis of azoisopropane in the presence of acrolein at 473-563 K. Reaction products were analyzed by gas chromatography. Rate constant ratios k , / k , = 0.02 lr 0.01 and k 4 / k 3 : 0.01 f 0.005 are suggested for the following reactions: (1) T