Electronic energy transfer in the gas phase: the quenching of O2(1Σ+g)
✍ Scribed by K. Kear; E.W. Abrahamson
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 495 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0047-2670
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molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A
The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected