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Role of the Metal and Surface Structure in the Electro-oxidation of Hydrazine in Acidic Media

✍ Scribed by Álvarez-Ruiz, B.; Gómez, R.; Orts, J. M.; Feliu, J. M.

Book ID
121787028
Publisher
The Electrochemical Society
Year
2002
Tongue
English
Weight
210 KB
Volume
149
Category
Article
ISSN
0013-4651

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Mechanistic Studies on the Oxidation of
Mechanistic Studies on the Oxidation of Hydrazine by Tris(biguanide)manganese(IV) in Aqueous Acidic Media
✍ Basab Bijayi Dhar; Ritam Mukherjee; Subrata Mukhopadhyay; Rupendranath Banerjee 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 90 KB

The title Mn IV complex, [Mn(LH 2 ) 3 ] 4 (LH 2 biguanide H 2 NC( NH)NHC( NH)NH 2 ), an authentic two-electron oxidant, quantitatively oxidizes hydrazine (H 2 NNH 2 ) to dinitrogen in the pH interval 2.00 ± 3.50. The net four-electron oxidation of hydrazine is provided by two Mn IV as established by