✦ LIBER ✦

Role of the entrance channel on the product internal energy distribution in the reaction: (Xe-Cl2)* → XeCl* + Cl

✍ Scribed by M. Boivineau; J. Le Calvé; M.C. Castex; C. Jouvet

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 374 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80667-4

No coin nor oath required. For personal study only.

✦ Synopsis

The Xe-Cl2 van der Waals complex formed in a supersonic expansion is excited by a two-photon process at 29'3.5 nm.

The XeCI* fragment obtained is vibrational& cold. This result is discussed and compared with those of the Xe* + Cl2 reaction and laser-assisted collision.

📜 SIMILAR VOLUMES

Observation of the intermediate states i

Observation of the intermediate states in the (Xe-Cl2)*→ XeCl* (B,C) + Cl reaction

✍ M. Boivineau; J. Le Calvé; M.C. Castex; C. Jouvet 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 422 KB

Control of product channels by addition

Control of product channels by addition of vibrational or electronic energy to the reactions of Xe(6s) atoms with CF3Cl, CF2Cl2 and CF2HCl molecules

✍ J. Xu; A.R. Slagle; D.W. Setser; J.C. Ferrero 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 799 KB

An order of magnitude enhancement of the XeCl(B,C) formation rate constants was observed for the 300 K reactions of Xe( 6p[ l/2] 0 and [ 3/2]\*) atoms with CF&l, CF& and CF,HCl, relative to the reactions of Xe( 6s, 3P2) atoms. Similar large XeCl( B,C) formation enhancement factors were found for rea

Reactions of Secondary Dithioxamides wit

Reactions of Secondary Dithioxamides with [(η6-p-cymene)RuCl(μ-Cl)]2: The Role of Steric Hindrance on Amidic Nitrogen in Determining the Reaction Products

✍ Santo Lanza; Giuseppe Bruno; Francesco Nicolò; Archimede Rotondo; Giuseppe Treso 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 368 KB 👁 1 views

Nascent rotational distribution of the m

Nascent rotational distribution of the minor v = 0 channel in the N+2 product of the Ar++ N2 charge transfer reaction at near thermal energy

✍ Guang-Hai Lin; Jürgen Maier; Stephen R. Leone 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 335 KB

An improved ion beam apparatus is used to study the nascent state distribution of products m the Ar+ + N, charge transfer reaction at 0.28 eV collision energy. The rotational distribution of the minor v = 0 vibrational channel under single-collision conditions can be characterized by ,a Boltzmann di

Effect of reagent rotational energy on p

Effect of reagent rotational energy on product-state distribution in the reaction Ca + HF → CaF + H

✍ R. Altkorn; F.E. Bartoszek; J. Dehaven; G. Hancock; D.S. Perry; R.N. Zare 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 418 KB

Dcparrrrwnr uf Cixrmistr> . Statr\_ford Unil ersirj . Smnford. Calijornia 9J305. US.4 Kecrnsd 15 \_aprrl 1963: in find1 form 31 May 19S3 The effect of reagent rotation on the product vibrstional state distribution is reported for the reaction Ca('S) + W(S lx+." = 1.J) -Cal'(S"+, u'.J') + II( An infr