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Role of Radical Cations in Aromatic Hydrocarbon Carcinogenesis

โœ Scribed by Ercole Cavalieri and Eleanor Rogan


Book ID
124276011
Publisher
Environmental Health Information Service
Year
1985
Tongue
English
Weight
679 KB
Volume
64
Category
Article
ISSN
0091-6765

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Deprotonation of hydrocarbon radical cat
โœ D.W. Werst; E.A. Piocos; E.E. Tartakovsky; A.D. Trifunac ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 697 KB

Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'