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Role of Intramolecular Torsion and Solvent Dynamics in the Charge-Transfer Kinetics in Triphenylphosphine Oxide Derivatives and DMABN

โœ Scribed by Changenet, Pascale; Plaza, Pascal; Martin, Monique M.; Meyer, Yves H.


Book ID
126254284
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
224 KB
Volume
101
Category
Article
ISSN
1089-5639

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The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p