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Pressure Tuning of Solvent Relaxation Time for the Excited Intramolecular Charge-Transfer Kinetics in 4-( N , N -Dimethylamino)triphenylphosphine in Alcohol

โœ Scribed by Kometani, Noritsugu; Kajimoto, Okitsugu; Hara, Kimihiko


Book ID
126171612
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
188 KB
Volume
101
Category
Article
ISSN
1089-5639

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The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p