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Role of Hyperconjugation in the 1,2-Shift Reactivity of Bicyclo[2.1.0]pentane and Cyclopropane Radical Cations: A Computational Study

✍ Scribed by Blancafort, Lluís; Williams, Ffrancon


Book ID
120014751
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
580 KB
Volume
116
Category
Article
ISSN
1089-5639

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On the question of 1,2 bridge shifts in
✍ Masayuki Kuzuya; Harold Hart 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 158 KB

In FSOsH/SO&lF at -50 to -100' the nonamethylbicyclo[3.2.1] octadien-2-yl cation 1 undergoes an nmr-observable reversible exchange process which equilibrates methyls 2,3,4,6 and 7 and methyls 8 and 9, but leaves the bridgehead methyls (1 and 5) unique.l CIRCUMAMBULATION 3 This observation was ration