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Does double hyperconjugation play a role in 1-bicyclo[2.2.2]octyl cation ? The through-space effect of polar substituents

✍ Scribed by G Wenke; D Lenoir


Book ID
108384864
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
267 KB
Volume
20
Category
Article
ISSN
0040-4039

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## Abstract A series of 10‐substituted(X)‐9‐trimethylstannyltriptycenes (2a) were synthesized and characterized and the ^119^Sn chemical shifts measured. Comparisons were made of the ^119^Sn substituent chemical shifts (SCS) of 2a and the corresponding values of 4‐substituted(X)bicyclo[2.2.2]oct‐1‐