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Role of frequency changes in vibrational energy transfer

✍ Scribed by H.K. Shin

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
513 KB
Volume
111
Category
Article
ISSN
0009-2614

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✦ Synopsis

The interaction potential energy tern1 quadratic in vibrational mordioatc is shown to CIUW a disturbanm in vibrational frequencies during the collision. It is showo in a semiclassical trealrnent that the disturbance QUSCS the frequencies lo change with time, and the effect of the time dependence on VT energy transfer is very important, while on VV processes it is not.

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