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Role of dialkyl aluminium chloride in polymerization of butadiene-1,3 under the influence of a titanium catalytic system of the Ziegler type

✍ Scribed by V.B. Murachev; M.V. Terganova; Ye.F. Shashkina; M.Yu. Ustenko; V.S. Byrikhin; A.N. Pravednikov

Book ID: 116048612
Publisher: Elsevier Science
Year: 1987
Weight: 376 KB
Volume: 29
Category: Article
ISSN: 0032-3950
DOI: 10.1016/0032-3950(87)90450-3

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## Abstract The additive effect of triphenylphosphine (Ph~3~P) was investigated in 1,3‐butadiene polymerization with cobalt dichloride (CoCl~2~) activated by methylaluminoxane (MAO); the catalytic system resulted in slowly‐initiated living polymerization with a high __cis__‐1,4 content (about 99%)