Ring-opening reactions of furfurylidenes
โ Scribed by Hoffman, Robert V.; Shechter, Harold
- Book ID
- 120816884
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 266 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## AlXll.Z& A series of epoxides from reaction of substituted deltacyclenes with metu-chloroperbenzoic acid are reported. These compounds were found to react with BFs.Et20 in MeOH/&O to yield ring-opened products. Rearrangements were noted in some cases depending on the substitution pattern. We
Treatment of 2-methyleneaziridines with chloroformates (MeO2CCI, PhCH202CCI) or acid chlorides (AcC1, p-NO2C6H4COCI) at room temperature in a variety of uonpolar solvents (CH2C12, THF, toluene) produces ring opened enamine products in moderate to good yields.
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