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Ring-Opening Reactions of Aziridines Fused to a Conformationally Locked Tetrahydropyran Ring

✍ Scribed by Jindřich Karban; Jiří Kroutil; Miloš Buděšínský; Jan Sýkora; Ivana Císařová

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
372 KB
Volume
2009
Category
Article
ISSN
1434-193X

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Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates α -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der